I have been casting for several years. The PVC works, yes the silicone works better, but at about $50 for a mold is it worth it? Yes if you plan on casting a lot of blanks. If you are not planning on 100's of blanks, the PVC works great, I split mine, tape them back together and then spray with mold release. Every so often I will have one stick, a rap with a hammer and it pops out.
My custom molds are made from silicone, I made my masters out of polished aluminum and other materials. Then I cast them myself. I have all of the equipment, not some jury rigged pressure or vacuum chambers. Professionally made to insure they won't blow up the neighborhood or kill me. The vacuum methods are relatively safe, if you want to play, go that route or spend a fortune.
I don't use the resins or Alumilite for call bodies, if I want acrylic look I will use acrylic, not the resin. I use the castings with worthless wood, cactus and other fillers, rarely by themselves. My castings are also used in some of my pens.
Marvin